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Постійне посилання на розділhttps://dspace.nuft.edu.ua/handle/123456789/7372

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20232

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Автор: search.filters.author.Medvedeva, AnzhelikaORCID: search.filters.orcid.https://orcid.org/0000-0001-8086-5351

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  • Ескіз
    Документ
    Theoretical description of sotolone electrochemical determination in wine in basic media over an undoped conducting polymer
    (2023) Tkach, Volodymyr; Kushnir, Marta; Kopiika, Vira; Luganska, Olga; Omelyanchyk, Lyudmyla; Kormosh, Zholt; Kucher, Mykhailo; Garcia, Jarem; Palamarek, Karina; Bagrii, Konon; Medvedeva, Anzhelika; Oliveira, Sílvio C.; Yagodynets, Petro; Niyazov, Laziz; Musayeva, Dilfuza; Samadov, Bakhodirjon; Payentko, Viktoriia; Demianenko, Eugeny; Paiva Martins, Jose Inacio Ferrao; Vaz dos Reis, Lucinda; Karputina, Margarita; Khargeliia (Karputina), Daria; Nazymok, Yevgeniya; Ivanushko, Yana; Palytsia, Yulia
    The electrochemical determination of sotolone in basic media over an undoped conducting polymer has been described for the first time. The alkaline hydrolysis, breaking the furanonic ring, leads to the appearance of an acid ion, entering the polymer matrix as a dopant. The stability analysis of the system, made by the development and investigation of the correspondent mathematical model, shows that the sotolon electrochemical determination is made efficiently. As for the oscillatory behavior, it may also be caused by the cyclic effect of chemical and electrochemical stages on the double electric layer capacitance and impedance.
  • Ескіз
    Документ
    The theoretical description of sucralose cathodic electrochemical determination over a poly(safranin) modified electrode in acidic media
    (2023) Tkach, Volodymyr; Storoshchuk, Nataliia; Storoshchuk, Bogdan; Oliveira, Sílvio C.; Kryvetskyi, Viktor; Kryvetska, Inna; Kryvetskyi, Igor; Yemelianenko, Nataliia; Narsiia, Valentyn; Yagodynets, Petro; Silva, Adriano; Masna, Zoriana; Shevchenko, Inna; Gnitsevych, Victoriya; Medvedeva, Anzhelika; Vasylieva, Olena; Musayeva, Dilfuza; Kosimov, Xayriddin; Jabborova, Oysha; Samadov, Bakhodirjon; Sagdullayeva, Gulandom; Hamdanova, Gulhayo; Karputina, Margarita; Khargeliia (Karputina), Daria; Garcia, Jarem; Odyntsova, Vira; Martins, José Inácio Ferrão da Paiva
    For the first time, sucralose cathodic electrochemical determination, assisted by the safranin-modified electrode in acidic solutions, has been theoretically described. The correspondent mathematical model analysis has shown that the steady-state stability range is wider than in most systems of electrochemical determination over the pyridinic nitrogen-containing conducting polymer. Moreover, the oscillatory behavior is less probable than in similar systems in acidic media. Nevertheless, it is more probable than in neutral media. Nevertheless, poly(safranin) is an efficient electrode modifier for sucralose electrochemical determination.