Synthesis and properties of 4-chloromethyl-6-hydroxycoumarins and 4-(2-benzofuryl)-6-hydroxycoumarins
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New 4-chloromethyl-6-hydroxycoumarins have been obtained by the condensation of hydroquinone derivatives with 4-chloroacetoacetic ester, and have been used for the synthesis of 4-(2-benzofuryl)-6-hydroxycoumarins. Alkylation and acylation of the phenolic hydroxyl of the synthesized 4-(2-benzofuryl)coumarins have been investigated.
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Frasinyuk, M. Synthesis and properties of 4-chloromethyl-6-hydroxycoumarins and 4-(2-benzofuryl)-6-hydroxycoumarins / M. Frasinyuk, S. Bondarenko, V. Khilya // Chemistry of Heterocyclic Compounds. – 2009. - № 45 – P. 290.