Aminomethylation of formononetin and cladrin by primary amines
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The reaction of natural isoflavones formononetin and cladrin with primary amines and formalin in the presence of a base catalyst was studied. Several novel substituted 9,10-dihydro-4H,8H-chromeno[8,7-e][1,3]oxazin-4-ones containing alkyl, benzyl, or heterylalkyl substituents in the N-9 position were synthesized.
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Bondarenko, S. Aminomethylation of formononetin and cladrin by primary amines / S. Bondarenko, M. Frasinyuk, V. Khilya // Chemistry of Natural Compounds. - 2009. - vol. 45. - № 4.