Synthesis of 5-nitro-N,N-diphenylhydrazinopyrimidines and investigation of their free radicals

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A number of 5-nitro-N,N-diphenylhydrazinopyrimidines were synthesized. Free radicals were obtaines by oxidation of these compounds with PbO2. The stabilities of 5-nitro-4-pyrimidinylhydrazyl radicals are close to the stability of the α,α-diphenyl--2,4-dinitrophenylhydrazyl radical. The structures of the compounds obtained were confirmed by the UV, IR, PMR and EPR spectra.

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Synthesis of 5-nitro-N,N-diphenylhydrazinopyrimidines and investigation of their free radicals / I. V. Boldyrev, O. M. Polumbrik, L. N. Markovskii, V. M. Cherkasov // Chemistry of Heterocyclic Compounds. - Nov 1980. - 16 (№ 11). - P. 1179-1183.

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