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  • Ескіз
    Документ
    Electrodeionization of li-containing solutions using ion exchange material based on tio2-mno2
    (2018) Chaban, Mariya; Rozhdestvenska, Lyudmyla; Dzyazko, Yulia
    In this work the problem of selective extraction of Li+ ions from combined solutions by electromembrane method is being solved. Sorbent based on lithium-substituted titanium manganese oxide was used. It is established that the function of the sorbent in the membrane system is reduced to the turbulization of the solution flow, but under the influence of alkalization of the solution near the surface of the sorbent granules, its sorption capacity increases with an increase in voltage from 3 to 20 V.
  • Ескіз
    Документ
    Electrodeionization removal of HCrO4- ions from diluted solution. Effect of membrane
    (2016) Dzyazko, Yulia; Arar, Özgur; Rozhdestvenska, Lyudmyla; Vasilyuk, Sergey
    Transport of chromate ions in the systems involving granulated ionexchangers and anion-exchange membranes of different origin was researched under various voltage. The role of the membranes as sorption barrier was considered. The method that allows one to estimate mobility of sorbed ions through ion-exchanger bed has been proposed. Electrodeionization of Cr(VI)- containing solution using inorganic ion exchange materials was studied.
  • Ескіз
    Документ
    Lithium-selective composite materials based on TiO2 and MnO2
    (2016) Rozhdestvenska, Lyudmyla; Chaban, Mariya; Belyakov, Volodymyr
    Ion-exchange materials based on titanium dioxide-manganese dioxide composite were synthesized by template method. It was proved that sorption characteristics of the obtained materials depend of rate of heat treatment during the synthesis. Higher temperatures promote agglomeration of sorbent and decrease in its kinetic characteristics. But more lithium-selective sorption centers are formed and the selectivity of sorption increases.